A window with daylight behind it
An exterior surface in sun is thousands of times brighter than an interior wall, and even a gray sky beats anything a scheme puts up. An accent that reads at night vanishes at noon.
That is a specification decision, not a failure. Either the object gets a level set against daylight, or the window gets a shade, or the emphasis is accepted as a night condition.
Reflected images of the source in glass and gloss
A specular reflection is an image of the source itself, carrying close to source luminance in a small area. A modest strip becomes a hard line in a glossy door or a stone counter, competing with whatever you were emphasizing.
The geometry is predictable, so do it on the drawing. Mirror the viewer's eye through the reflective plane and draw a line from that point; if it reaches the emitter, that seat sees it. Fix the angle, not the output.
The brightest matte surface in the frame
This is the level you actually control. A wall or ceiling wash sets the reference, and the accent is read against it rather than against any absolute figure.
Which leads to the move most schemes miss. If the accent is already at the top of its output, drop the surround instead: it is the cheaper half of the ratio, and contrast is what reads. Accent to surround ratios in the 3:1 to 10:1 band are a design convention rather than a published specification, so set them by eye. That needs the accent and the surround on separate channels: the controllers that can hold separate levels include multi-channel units such as the EnoSync Hub5 listing, with channel count and per-channel current confirmed there.
Nothing in that chain crosses voltages, so a 24V accent run takes a 24V supply and a 24V controller, and a 12V run takes the 12V counterpart of each. Where the surround is dimmed, verify the whole combination against the documentation for each device, the driver, the controller, the wall plate and the tape, since a dimmable label on each proves nothing about the set. Dimming a surround usually means a wall device, and fitting one is line voltage work: a licensed electrician handles the wall plate, any hardwired driver and the junction box, under local code, under NEC requirements where they apply, and under the documentation issued for each device, with the circuit off at the panel and proven dead before the box is opened. None of the low voltage guidance here is clearance for that. The layers themselves are covered in how ambient, task and accent levels sit against each other.
Edges where luminance changes fastest
A boundary where brightness changes sharply over a short distance stands out even at modest levels. A tight pool with a hard edge competes with a far larger, softer wash at the same peak.
That cuts both ways. Where a small object has to hold its own in a bright room, give it a hard edge: a narrow distribution, a shielded aperture, a run stopping cleanly at the object. Where the light should not be noticed, let it arrive as a gradient. See what a beam angle figure describes.
Placing light for emphasis once the competition is dealt with
With the emitters shielded, the daylight accounted for, the reflections steered away and the surround low, the last step is easy: light the object from one dominant direction, above the surround, and leave some shadow on it.
Direction is what makes a three-dimensional object read as three-dimensional. A source in the 30 to 45 degree band off the face keeps one side lit and the other in shadow; light it flat from the front and it goes flat. Test that band in place. If the positions are still open, we can work from a photo taken at the doorway.